Postfix Mail Relay in a few easy steps [CentOS 6 tested]
First of all we install postfix package (if not already installed):
Common Zimbra outgoing mail issues behind NAT
Setup Zimbra Collaboration Suite on a cloud server without public interface (read: behind NAT) may waste you an afternoon trying to figure out why local emails (same domain) are not delivered, while sending/receiving mail from/to the internet works flawless.